Overcoming double-step CO2 adsorption and minimizing water co-adsorption in bulky diamine-appended variants of Mg2(dobpdc)† †Electronic supplementary information (ESI) available: Additional experimental details, and full characterization (powder X-ray diffraction, infrared spectra, diamine loadings, dry N2 decomposition profiles, and CO2 adsorption data) for all new adsorbents. CCDC 1577354. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc04266c

Mixed-valent, heteroleptic homometallic diketonates as templates for the design of volatile heterometallic precursors† †Electronic supplementary information (ESI) available: Experimental procedures, synthetic details, IR spectra, X-ray powder diffraction patterns, computational details, TEM images and phase analysis of thermal decomposition products. CCDC 1040548–1040553. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc04002c

Hyperfine adjustment of flexible pore-surface pockets enables smart recognition of gas size and quadrupole moment† †Electronic supplementary information (ESI) available: Experimental section, PXRD patterns, crystallographic tables and characterization details. CCDC 1561837–1561845. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc03067c Click here for additional data file. Click here for additional data file.

The pore size and framework flexibility of hosts are of vital importance formolecular recognition and related applications, but accurate control of these parameters is very challenging. We use the slight difference of metal ion size to achieve continuous hundredth-nanometer pore-size adjustments and drastic flexibility modulations in an ultramicroporous metal–organic framework, giving controlla...

Triple aryne–tetrazine reaction enabling rapid access to a new class of polyaromatic heterocycles† †Electronic supplementary information (ESI) available: Experimental protocols, characterization data, X-ray crystallographic data (CIF) and NMR spectra of all new compounds. CCDC 1400529. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01726b Click here for additional data file. Click here for additional data file.

Structural characterization of framework–gas interactions in the metal–organic framework Co2(dobdc) by in situ single-crystal X-ray diffraction† †Electronic supplementary information (ESI) available: Supplementary figures, crystallographic information, adsorption isotherms and fits, CCDC 1530119–1530126. For ESI and crystallographic data in CIF or other electronic format. See DOI: 10.1039/c7sc00449d Click here for additional data file. Click here for additional data file.

aDepartment of Chemistry, University of California, Berkeley, California, 94720-1462, USA. bAdvanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California, 94720, USA. cThe Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, California, 94720, USA. dÉcole Polytechnique Fédérale de Lausanne (EPFL), Institut des Sciences et Ingénierie Chimiques, CH 1051 Sion, S...

Photoinduced water oxidation by an organic ligand incorporated into the framework of a stable metal–organic framework† †Electronic supplementary information (ESI) available: Additional structure figures, TGA curve, adsorption isotherms, UV-vis spectra, ESR spectra, GC spectra, PXRD patterns, and an additional cyclic voltammogram. CCDC 1003764. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc02679b Click here for additional data file. Click here for additional data file.